nav emailalert searchbtn searchbox tablepage yinyongbenwen piczone journalimg journalInfo journalinfonormal searchdiv searchzone qikanlogo popupnotification paper paperNew
2021, 06, v.41 566-570
等离子体增强原子层沉积增透阻隔膜的研究
基金项目(Foundation): 黑龙江省教育厅省属高校科技成果研发支持计划(TSTAU-R2018009)
邮箱(Email): linlin681020@126.com;
DOI: 10.13922/j.cnki.cjvst.202007053
摘要:

高阻隔高透光率的柔性复合材料在包装和电子封装领域具有很高的应用价值。本文采用等离子增强原子层沉积技术在PET基体上制备了多层结构的增透阻隔膜,研究了等离子增强原子层沉积制备氧化硅和氮化硅的工艺参数,利用光学模拟软件设计出所需透过率的膜层结构。结果表明:等离子体增强原子层沉积制备的薄膜原子力显微镜表面形貌晶粒分布均匀,薄膜致密,红外光谱显示制备的薄膜为高纯度的SiO2和Si_3N4,薄膜的透水率降低了2个数量级,可见光范围透过率可达到94%。

Abstract:

Flexible composite materials with high barrier and high light transmittance have high application value in packaging and electronic packaging.In this paper,plasma-enhanced atomic layer deposition technology was used to prepare a multilayer antireflection barrier film on the PET substrate.The process parameters of plasmaenhanced atomic layer deposition to prepare silicon oxide and silicon nitride were studied,and optical simulation software was used to design the required transparency film structure.The results show that the surface morphology of the film AFM prepared by plasma enhanced atomic layer deposition is uniform and the film is dense.The infrared spectrum shows that the prepared film is high-purity SiO2 and Si_3N4.The water permeability of the film is reduced by 2 orders of magnitude,and the visible light range The transmittance can reach 94%.

参考文献

[1]顾春生.真空镀膜在高阻隔性包装材料上的应用[J].塑料包装,2014,24(3):31-35

[2]刘向红,张薇蓉.复合高阻隔片材应用于巴氏杀菌酸奶包装的研究[J].包装工程,2015,36(7):5-10

[3]林晶,董文丽,孙智慧,等.新型高阻隔陶瓷薄膜包装材料及技术[J].包装工程,2007,28(10):99-102

[4]杨丽娟.太阳能电池封装用透明热塑性聚氨酯薄膜的制备、性能与应用研究[D].广州:华南理工大学,2017

[5]李旺,朱登华,刘石勇,等.PI衬底柔性透明硅薄膜太阳能电池的制备及性能[J].电子元件与材料,2015,34(08):34-37

[6]Hanbin Lee,Minjeong Park,Minhyon Jeon,et al.MultiLayer Anti-Reflection Film Based on SiOx and NbOx by DC Pulse Sputter System with Inductively Coupled[J].Plasma Source,2020,10(6):424

[7]Jinyong Jung,June-Seo Kim,Joonwoo Kim,et al.Enhancement of Brillouin Light Scattering Signal with Antireflection Layers on Magnetic Thin Films[J].Journal of Magnetism and Magnetic Materials,2020:502

[8]Yunfei Xu,Jing Zhang,Ling Ai,et al.Fabrication of Mesoporous Double-Layer Antireflection Coatings with Nearneutral Color and Application in Crystalline Silicon Solar Modules[J].Solar Energy,2020:201

[9]Gazi A.K.M.Rafiqul Bari,Haekyoung Kim.High-Refractive-Index and High Barrier-Capable Epoxy-Phenoxybased Barrier Film for Organic Electronics[J].Polymers for Advanced Technologies,2020,31(8):1752-1764

[10]George S.M.Atomic Layer Deposition:an Overview[J].Chemical Reviews,2010,110(1):111-131

[11]Gougousi T.Atomic Layer Deposition of High-k Dielectrics onⅢ-V Semiconductor Surfaces[J].Progress in Crystal Growth&Characterization of Materials,2016,62(4):1-21

[12]Kim J B,Kwon D R,Chakrabarti K,et al.Improvement in Al2O3Dielectric Behavior by Using Ozone as an Oxidant for the Atomic Layer Deposition Technique[J].Journal of Applied Physics,2002,92(11):6739-6742

[13]Profijt H B,Potts S E,Vande Sanden M C M,et al.Plasma-Assisted Atomic Layer Deposition:Basics,Opportunities,and Challenges[J].Journal of Vacuum Science and Technology A,2011,29(5):050801-050826

[14]SIMON D K,JORDAN P M,KNAUT M,et al.ALDAl2O3 Based Nanolaminates for Solar Cell Applications[C]Photovoltaic Specialist Conference,2015

[15]WANG X,DUAN Y H,CHEN Z,et al.A Flexible Transparent Gas Barrier Film Employing the Method of Mixing ALD/MLD-Grown Al2O3and Alucone Layers[J].Nanoscale Research Letters,2015,10(1):130

[16]魏海英,郭红革,秦莹莹,等.大气压介质阻挡放电等离子体辅助原子层沉积氧化铝阻隔膜[J].材料导报,2018,32(S2):311-314

[17]方明.离子体辅助TMA催化TPS快速原子层沉积SiO2研究[D].北京:北京印刷学院,2015

基本信息:

DOI:10.13922/j.cnki.cjvst.202007053

中图分类号:TB383.2

引用信息:

[1]林晶,于贵文,孙智慧,等.等离子体增强原子层沉积增透阻隔膜的研究[J].真空科学与技术学报,2021,41(06):566-570.DOI:10.13922/j.cnki.cjvst.202007053.

基金信息:

黑龙江省教育厅省属高校科技成果研发支持计划(TSTAU-R2018009)

发布时间:

2021-06-15

出版时间:

2021-06-15

检 索 高级检索

引用

GB/T 7714-2015 格式引文
MLA格式引文
APA格式引文