2025 01 v.45 8-13
磁控溅射过渡层对CFRP筒体内壁电镀Ni金属涂层结合性能的影响
基金项目(Foundation):
粒子输运与富集技术国防科技重点实验室开放课题研究基金（SYSKFJ2022）;
西物创新行动项目（202301XWCX003）
邮箱(Email):
yafanjin@163.com;
DOI:
10.13922/j.cnki.cjvst.202405008
中文作者单位:
核工业西南物理研究院;核工业理化工程研究院;
摘要(Abstract):
对碳纤维增强树脂基复合材料筒体内壁表面进行金属化处理，通过射频等离子体活化、磁控溅射沉积过渡层金属、电镀沉积镍三个步骤在碳纤维复合材料筒体内壁制备大厚度、高结合强度的金属涂层。以拉拔法测试涂层与基体之间的结合强度，探究Cu、Ti-Cu过渡层及不同过渡层厚度对金属涂层结合强度的影响。采用扫描电镜及配套的能谱仪观测金属涂层表面微观形貌和截面元素组成，采用X射线衍射仪分析金属涂层的晶体结构。结果表明，磁控溅射Ti-Cu过渡层能明显提高电镀Ni金属涂层与基体之间的结合强度，钛膜层厚度对电镀Ni金属涂层结合强度的影响很大，铜膜层厚度对结合强度相对较小，结合强度随着铜膜层的增厚而降低。在等离子体活化的基础上，通过磁控溅射在CFRP筒体内壁制备0.2μm Ti+1μm Cu的过渡层，使电镀约17μm Ni金属涂层的结合强度达到2.05 MPa，赋予了碳纤维复合材料筒体内壁金属特性。
关键词(KeyWords):
碳纤维复合材料;筒内壁;过渡层;结合强度;表面金属化
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参考文献
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[2]Malinowski P,Wandowski T,Ostachowicz W.The use of electromechanical impedance conductance signatures for detection of weak adhesive bonds of carbon fibre-reinforced polymer[J].Structural Health Monitoring,2015,14(4):332-344
[3]Jaeschke P,Wippo V,Suttmann O,et al.Advanced laser welding of high-performance thermoplastic composites[J].Journal of Laser Applications,2015,27(S2):S29004
[4]Zhang K,Zhang D,Zou R R,et al.Application research progress of CFRP in automobile lightweight[J].Engineering Plastics Application,2022,50(10):154-158+163（张坤,张丹,邹瑞睿,等.CFRP在汽车轻量化中的应用研究进展[J].工程塑料应用，2022,50(10):154-158+163(in Chinese））
[5]Zhong M J,Hu W J,Liao X T,et al.Present situation and development trend of processing technology of carbon fiber composite parts[J].Engineering Plastics Application,2022(5):110-119（钟明建,胡炜杰,廖晓恬,等.碳纤维复合材料部件加工技术现状及发展趋势[J].Composites Science And Engineering,2022(5):110-119 (in Chinese））
[6]He W F,Li R K,Luo S H.Progress in plasma surface treatment on carbon fiber for composite material[J].Surface Technology,2020,49(7):76-89（何卫锋,李榕凯,罗思海.复合材料用碳纤维等离子体表面改性技术进展[J].表面技术，2020,49(7):76-89 (in Chinese））
[7]Liu X,Zhang Z T,Liu J Y,et al.Effect of helium/oxygen mixed plasma jet on cfrp surface properties and bonding strength[J].Surface Technology,2022,51(1):247-256（刘新,张忠涛,刘吉宇,等.混氧等离子体射流对CFRP表面性质及粘接强度的影响[J].表面技术，2022,51(1):247-256 (in Chinese））
[8]Zou T C,Liu Z H,Li Y,et al.Effect of plasma surface treatment on bonding properties and surface properties of CFRP[J].China Surface Engineering,2022,35(1):125-134（邹田春,刘志浩,李晔,等.等离子体表面处理对碳纤维增强树脂基复合材料（CFRP）胶接性能及表面特性的影响[J].中国表面工程，2022,35(1):125-134(in Chinese））
[9]Lin J,Sun C,Min J,et al.Effect of atmospheric pressure plasma treatment on surface physicochemical properties of carbon fiber reinforced polymer and its interfacial bonding strength with adhesive[J].Composites Part B:Engineering,2020,199:108237
[10]Kim J T,Park C W,Kim B-J.A study on synergetic EMIshielding behaviors of Ni-Co alloy-coated carbon fibersreinforced composites[J].Synthetic Metals,2017,223:212-217
[11]Wan J H,Dan M,Huang J J,et al.Plasma treatment on the activation effect of the inner wall of CFRP cylindrical parts[J].China Surface Engineering,2023,36(6):178-185（万俊豪,但敏,黄佳俊,等.等离子体处理对CFRP筒状件内壁活化效果的影响[J].中国表面工程，2023,36(6):178-185 (in Chinese））
[12]Cui W,Qin G,Duan J,et al.A graded nano-TiN coating on biomedical Ti alloy:Low friction coefficient,good bonding and biocompatibility[J].Materials Science and Engineering:C,2017,71:520-528
[13]Wu Y,Zhao J,Li Y F.Effect of thickness of transition layer on bonding strength of DLC film[J].Hot Working Technology,2018,47(20):141-143（吴雁,赵杰,李艳峰.过渡层厚度对类金刚石薄膜结合强度的影响[J].热加工工艺，2018,47(20):141-143 (in Chinese））
[14]Ali R,Sebastiani M,Bemporad E.Influence of Ti-TiNmultilayer PVD-coatings design on residual stresses and adhesion[J].Materials&Design,2015,75:47-56
[15]Ni X L.The surface functional coating preparation on carbon fiber/resin composites[D].Hefei:University of Science and Technology of China,2015（倪新亮.碳纤维增强树脂基复合材料表面功能涂层制备研究[D].合肥:中国科学技术大学,2015 (in Chinese））
[16]Li Y,Wang H B,Gao W D,et al.The study of carbon fibers with magnetron sputtered copper coating[J].New Chemical Materials,2011,39(12):62-63+86（李颖,王鸿博,高卫东.碳纤维表面磁控溅射镀铜研究[J].化工新型材料，2011,39(12):62-63+86 (in Chinese））
[17]Li J K,Wang Y N,Wang R Y,et al.Conductivity and wettability of copper-plated wood veneer with magnetron sputtering[J].Journal of Northeast Forestry University,2019,47(4):86-90（李景奎,王亚男,王若颖,等.磁控溅射镀铜木材单板导电性能和润湿性能[J].东北林业大学学报，2019,47(4):86-90 (in Chinese））
[18]Liu S F,Shen Y F,Wang S G.Microstructure analyse of surface Ti-metallized graphite[J].Transactions of the China Welding Institution,2005(12):89-92+127（刘仕福,沈以赴,王少刚.石墨表面钛金属化微观组织分析[J].焊接学报，2005(12):89-92+127 (in Chinese））
[19]Yang L,Pan Y J,Zheng S E,et al.Structure and process parameters of titanium films prepared by magnetron sputtering on graphite[J].Plating and Finishing,2023,45(3):11-17（杨岭,潘应君,郑世恩,等.石墨表面磁控溅射钛膜的结构与工艺参数研究[J].电镀与精饰，2023,45(3):11-17 (in Chinese））
[20]Zhao D C,Xiao G J,Ma Z J,et al.Properties of al film on composite with Ti interlayer[J].Rare Metal Materials and Engineering,2013,42(S2):243-246
基本信息:
DOI：10.13922/j.cnki.cjvst.202405008
中图分类号:TB306;TB332
引用信息:
[1]万俊豪,杨洋,但敏等.磁控溅射过渡层对CFRP筒体内壁电镀Ni金属涂层结合性能的影响[J].真空科学与技术学报,2025,45(01):8-13.DOI:10.13922/j.cnki.cjvst.202405008.
基金信息:
粒子输运与富集技术国防科技重点实验室开放课题研究基金（SYSKFJ2022）; 西物创新行动项目（202301XWCX003）